As described:
You should setup a new location specifically for catalyst and only include the ports in use
Disable or turn off any others
Anything with DHCP will take priority over a static IP address (wifi) - so turn off any adaptors not in use and use static IP addresses.

So long as you have the correct IP address and subnet it will work

…Again - It doesn't matter what the catalyst control window says

What are you trying to achieve?

S