You need to sync the content as well as the cue for this to happen
Use m364
Change your playmode to 72 - 'sync to smpte L auto load offset'
Enter the timecode start value for each clip in the library HUD
You may also need to check the options on the timecode device in the catalyt control window
Ensure that you have sufficient preroll - never start at zero - always add min 5 second preroll to ensure that smpte is running correctly and you hit your cue
Also see previous thread with more info...
samsc.com/showpost.php?p=10781&postcount=22
S